I really appreciate all the input on what may be causing this problem, my shop manual does not always have good trouble solution information and I find that most often the best answers will come from other Buick owners who may have experienced the same problem or one close to it. This leak from the over flow pipe was being caused by problems in the heat conrtol valve or the heater core. Have not determined which one yet. After doing testing for what may be a leaking head gasket, the one recommended by Jay and a similar test described in the shop manual, I ruled out a possible head gasket leak and moved on to checking out the areas around the freeze plugs and the heater core. The temperture control knob for the heat control valve which is always turned off, was turned over to the warmest setting, but I had not noticed any heat while driving. After turning the control valve off I started the engine, let it run for about 10 minutes and there was no water leaking from the over flow pipe. I took a 20 minute drive, shut the enging off and still no water leak. I only drive this car in late spring, summer and fall and do not need or use the heater, so depending on what it takes to repair or replace the control valve and/or heater core, I may just make sure the control valve is always off or disconnect the temperture control knob, untill some time later.